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Question 1
ప్రశ్న 1
What is meant by total hardness of water in conventional water-treatment calculations?
Explanation:
Hardness is caused principally by dissolved multivalent cations, especially calcium and magnesium in ordinary natural waters. For engineering calculations, the contributions of calcium and magnesium are converted to a common CaCO3 equivalent basis. Their sum is then reported as total hardness in mg/L as CaCO3. This common basis allows different ionic species to be compared stoichiometrically. Therefore Option A is correct.
వివరణ:
Question 2
ప్రశ్న 2
Under the currently applicable IS 10500 drinking-water specification, what are the acceptable and permissible limits in the absence of an alternate source for total hardness as CaCO3?
Explanation:
The current acceptable limit for total hardness under IS 10500 is 200 mg/L as CaCO3. The permissible limit in the absence of an alternate source is 600 mg/L as CaCO3. These values should not be confused with the limits for total dissolved solids, which are different. Hardness is important mainly because of scaling, soap consumption and operational effects rather than being interpreted like an acute toxic contaminant. Therefore Option C is correct.
వివరణ:
Question 3
ప్రశ్న 3
According to current MoHUA/CPHEEO guidance, how is water having a total hardness of 220 mg/L as CaCO3 classified?
Explanation:
Current CPHEEO guidance classifies water below 50 mg/L as CaCO3 as soft. Water from 50 to 150 mg/L is classified as moderately hard. The hard category extends from 150 to 300 mg/L, while values above 300 mg/L are very hard. A value of 220 mg/L lies within the 150 to 300 mg/L range. Therefore Option C is correct.
వివరణ:
Question 4
ప్రశ్న 4
Which statement is consistent with current CPHEEO guidance regarding domestic softening need?
Explanation:
Current CPHEEO guidance notes that domestic softening is not usually required when hardness is below approximately 150 mg/L as CaCO3. This does not mean that every water above 150 mg/L must automatically be softened. Treatment selection should consider user requirements, scaling potential, source characteristics, economics and the intended use of the water. Industrial processes may require much lower hardness than ordinary domestic supplies. Therefore Option B is correct.
వివరణ:
Question 5
ప్రశ్న 5
When total hardness and total alkalinity are both expressed as CaCO3, which relation is conventionally used to separate carbonate and non-carbonate hardness?
Explanation:
Carbonate hardness is associated with hardness balanced by carbonate and bicarbonate alkalinity. It therefore cannot exceed either total hardness or total alkalinity when both are expressed on the same CaCO3 basis. The carbonate hardness is consequently taken as the smaller of these two values. Any remaining hardness is classified as non-carbonate hardness. Therefore Option A is correct.
వివరణ:
Question 6
ప్రశ్న 6
A water has total hardness of 320 mg/L as CaCO3 and total alkalinity of 180 mg/L as CaCO3. What are its carbonate hardness and non-carbonate hardness?
Explanation:
Carbonate hardness is the smaller of total hardness and total alkalinity. The smaller value here is 180 mg/L as CaCO3. Non-carbonate hardness is therefore 320 - 180 = 140 mg/L as CaCO3. The two components correctly add back to the total hardness of 320 mg/L. Therefore Option B is correct.
వివరణ:
Question 7
ప్రశ్న 7
A water sample contains 40 mg/L of calcium ion. Using an equivalent weight of 20 for Ca2+, what calcium hardness is this equivalent to as CaCO3?
Explanation:
Hardness is converted to CaCO3 equivalents using the ratio 50 divided by the equivalent weight of the ion. For calcium, the stated equivalent weight is 20. The conversion factor is therefore 50/20 = 2.5. Thus 40 × 2.5 = 100 mg/L as CaCO3. Therefore Option C is correct.
వివరణ:
Question 8
ప్రశ్న 8
A water sample contains 24 mg/L of magnesium ion. Using an equivalent weight of 12 for Mg2+, what magnesium hardness is this equivalent to as CaCO3?
Explanation:
The CaCO3-equivalent concentration is obtained by multiplying the ion concentration by 50 divided by its equivalent weight. For magnesium, the equivalent weight is stated as 12. The conversion factor is therefore 50/12. Multiplying 24 mg/L by this factor gives exactly 100 mg/L as CaCO3 under the stated approximation. Therefore Option C is correct.
వివరణ:
Question 9
ప్రశ్న 9
A water contains 48 mg/L Ca2+ and 24 mg/L Mg2+. Using equivalent weights of 20 and 12 respectively, what are the total hardness and its CPHEEO hardness classification?
Explanation:
The calcium hardness is 48 × 50/20 = 120 mg/L as CaCO3. The magnesium hardness is 24 × 50/12 = 100 mg/L as CaCO3. Total hardness is therefore 120 + 100 = 220 mg/L as CaCO3. Current CPHEEO classification places 150 to 300 mg/L in the hard-water category. Therefore Option C is correct.
వివరణ:
Question 10
ప్రశ్న 10
Which statement best describes the basic removal mechanism of lime-soda softening?
Explanation:
Lime-soda softening is a chemical-precipitation process. Suitable alkaline conditions convert calcium hardness to sparingly soluble calcium carbonate. Magnesium is removed principally by precipitation as magnesium hydroxide at sufficiently high pH. Soda ash supplies carbonate where needed to precipitate non-carbonate calcium hardness. Therefore Option A is correct.
వివరణ:
Question 11
ప్రశ్న 11
For a lime-soda calculation, a water contains 120 mg/L calcium carbonate hardness, 60 mg/L magnesium carbonate hardness, 80 mg/L calcium non-carbonate hardness and 40 mg/L magnesium non-carbonate hardness, all expressed as CaCO3. Neglect CO2, acidity and other chemical demands. What are the theoretical requirements of pure Ca(OH)2 and pure Na2CO3?
Explanation:
For the stated simplified case, lime as Ca(OH)2 is 0.74 times the sum of calcium carbonate hardness, twice the magnesium carbonate hardness and magnesium non-carbonate hardness. Thus the lime-equivalent hardness is 120 + 2(60) + 40 = 280 mg/L as CaCO3, giving 0.74 × 280 = 207.2 mg/L Ca(OH)2. Soda ash is required for the calcium and magnesium non-carbonate hardness, giving 1.06 × (80 + 40). This equals 127.2 mg/L Na2CO3. Therefore Option B is correct.
వివరణ:
Question 12
ప్రశ్న 12
A 12 MLD plant treats the water in the previous question using theoretical doses of 207.2 mg/L Ca(OH)2 and 127.2 mg/L Na2CO3. What pure chemical quantities are required per day?
Explanation:
A dosage of 1 mg/L applied to 1 MLD corresponds numerically to 1 kg/day. Therefore the lime requirement is 207.2 × 12 = 2,486.4 kg/day. The soda-ash requirement is 127.2 × 12 = 1,526.4 kg/day. These figures represent pure chemical requirements before correction for commercial purity. Therefore Option A is correct.
వివరణ:
Question 13
ప్రశ్న 13
If the lime requirement is 2,486.4 kg/day of pure Ca(OH)2 and the commercial lime is 90% pure, while the soda requirement is 1,526.4 kg/day of pure Na2CO3 and commercial soda ash is 95% pure, what commercial masses are approximately required?
Explanation:
The commercial mass must be larger than the pure requirement when chemical purity is below 100 percent. The lime requirement is 2,486.4/0.90 = approximately 2,762.7 kg/day. The soda-ash requirement is 1,526.4/0.95 = approximately 1,606.7 kg/day. Multiplication of these commercial quantities by their respective purity fractions returns the required active chemical masses. Therefore Option B is correct.
వివరణ:
Question 14
ప్రశ్న 14
Why does magnesium carbonate hardness require twice the lime equivalent used for calcium carbonate hardness in the conventional stoichiometric lime-soda calculation?
Explanation:
Magnesium bicarbonate hardness cannot be removed simply by forming calcium carbonate. Lime first reacts with the bicarbonate system and also generates conditions for conversion of magnesium to magnesium hydroxide. An additional hydroxide requirement is therefore associated with precipitation of Mg2+ as Mg(OH)2. The resulting stoichiometry gives twice the lime demand, on a CaCO3-equivalent basis, compared with calcium carbonate hardness. Therefore Option A is correct.
వివరణ:
Question 15
ప్రశ్న 15
Which statement correctly describes the practical residual-hardness limitation of lime-soda softening under current CPHEEO guidance?
Explanation:
Lime-soda softening depends on precipitation of calcium carbonate and magnesium hydroxide. Because these precipitates possess finite solubility and real treatment reactions are not infinitely complete, some residual hardness remains. Current CPHEEO guidance states that lime-soda softening cannot reduce hardness to values below approximately 40 mg/L. Ion-exchange softening can achieve essentially zero-hardness water because it removes hardness ions through exchange rather than precipitation equilibrium. Therefore Option B is correct.
వివరణ:
Question 16
ప్రశ్న 16
What is the principal purpose of recarbonation following lime or lime-soda softening?
Explanation:
Lime softening commonly leaves the treated water at an elevated pH and potentially supersaturated with calcium carbonate. Carbon dioxide is introduced during recarbonation to neutralize excess hydroxide and convert carbonate species toward bicarbonate. This lowers pH and improves chemical stability before filtration or distribution. Proper recarbonation reduces the tendency for unwanted calcium-carbonate deposition in downstream units and pipelines. Therefore Option A is correct.
వివరణ:
Question 17
ప్రశ్న 17
What is the fundamental softening mechanism in the sodium-zeolite process?
Explanation:
Sodium zeolite contains exchangeable sodium ions associated with the exchanger structure. As hard water passes through the bed, calcium and magnesium have a stronger affinity for the exchange sites. These hardness-producing ions are retained while equivalent sodium ions are released to the water. The process therefore removes hardness without creating the large precipitation sludge associated with lime-soda treatment. Therefore Option A is correct.
వివరణ:
Question 18
ప్రశ్న 18
How is an exhausted sodium-zeolite softening bed normally regenerated?
Explanation:
During service, calcium and magnesium progressively occupy the exchange sites of sodium zeolite. Regeneration requires restoring sodium ions to those sites. A concentrated sodium chloride brine provides a large sodium concentration that drives the exchange reaction in the reverse direction. Calcium and magnesium are released into the regenerant waste while the bed returns to the sodium form. Therefore Option A is correct.
వివరణ:
Question 19
ప్రశ్న 19
Which statement about total dissolved solids during sodium-cycle zeolite softening is most accurate?
Explanation:
Sodium-cycle softening is an ion-substitution process rather than a complete salt-removal process. Calcium and magnesium ions are retained by the exchanger while sodium ions enter the water. The total amount of dissolved ionic material is therefore not removed in the manner achieved by demineralization or membrane desalination. Consequently sodium zeolite softening can produce very low hardness without producing demineralized water. Therefore Option B is correct.
వివరణ:
Question 20
ప్రశ్న 20
Which statement correctly describes the sodium and hydrogen cycles of ion-exchange softening?
Explanation:
Ion exchange is a reversible process in which the exchange medium can be restored after exhaustion. In the sodium cycle, hardness cations displace sodium from the exchanger and sodium chloride is commonly used for regeneration. In a hydrogen-cycle cation exchanger, cations are exchanged for hydrogen ions instead. Acid is used to regenerate the hydrogen form of the exchanger. Therefore Option A is correct.
వివరణ:
Question 21
ప్రశ్న 21
A raw water has total hardness above 700 mg/L as CaCO3 and also contains significant turbidity, colour and iron. Which treatment selection is most consistent with current CPHEEO guidance?
Explanation:
Current CPHEEO guidance notes that lime-soda softening is particularly applicable to waters with very high initial hardness. It also identifies turbidity, colour and iron as characteristics that can interfere with ion-exchange media by coating or fouling the granules. Chemical precipitation can simultaneously assist removal of some of these interfering constituents. The actual process must still be selected from complete raw-water analysis, treatment objectives and economics. Therefore Option A is correct.
వివరణ:
Question 22
ప్రశ్న 22
A zero-hardness ion-exchange effluent is blended with untreated water having hardness 300 mg/L as CaCO3. What blend of untreated and softened water will produce a final hardness of 90 mg/L, assuming linear mixing and no other hardness source?
Explanation:
Let the untreated-water fraction be x. Its hardness contribution is 300x mg/L, while the zero-hardness softened stream contributes no hardness. Setting 300x equal to the desired 90 mg/L gives x = 0.30. Thus the blend requires 30 percent untreated water and 70 percent softened water. Therefore Option B is correct.
వివరణ:
Question 23
ప్రశ్న 23
An ion-exchange bed has a usable hardness-removal capacity equivalent to 50 kg of CaCO3 before regeneration. If the incoming water hardness is 250 mg/L as CaCO3 and complete hardness removal is assumed, what water volume can be treated before the stated capacity is exhausted?
Explanation:
An influent hardness of 250 mg/L equals 0.25 kg of hardness as CaCO3 per cubic metre of water. The exchanger can remove a total of 50 kg as CaCO3 before regeneration. The treatable volume is therefore 50/0.25 = 200 m3. This simplified calculation assumes the stated capacity is fully usable and that hardness is removed completely until exhaustion. Therefore Option C is correct.
వివరణ:
Question 24
ప్రశ్న 24
Why does magnesium non-carbonate hardness consume both lime and soda ash in a conventional lime-soda calculation?
Explanation:
Consider a magnesium salt such as magnesium sulphate as an example of non-carbonate hardness. Lime supplies hydroxide that precipitates magnesium as Mg(OH)2. The accompanying anion then remains associated with calcium introduced by the lime, producing calcium non-carbonate hardness such as CaSO4. Soda ash supplies carbonate so that this calcium can subsequently precipitate as CaCO3. Therefore Option A is correct.
వివరణ:
Question 25
ప్రశ్న 25
Consider the following statements about water softening: I. Carbonate hardness is limited by alkalinity when hardness and alkalinity are expressed as CaCO3. II. Lime-soda treatment removes calcium principally as CaCO3 and magnesium principally as Mg(OH)2. III. Sodium zeolite exchanges Ca2+ and Mg2+ for Na+ and is regenerated with brine. IV. Current CPHEEO guidance states that lime-soda softening cannot practically produce zero-hardness water, whereas ion exchange can. Which option is correct?
Explanation:
Statement I is correct because carbonate hardness cannot exceed the alkalinity available to balance hardness cations. Statement II correctly identifies the principal precipitates formed during lime-soda softening. Statement III correctly describes sodium-cycle base exchange and its common sodium-chloride regeneration method. Statement IV agrees with current CPHEEO guidance on the practical residual-hardness limits of precipitation softening and the capability of ion exchange. Therefore all four statements are correct and Option D is the valid answer.
వివరణ:
Answer Key సమాధానాల పట్టిక
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Question 1 ప్రశ్న 1Answer: A. The combined calcium and magnesium hardness, conventionally expressed as an equivalent concentration of CaCO3 సమాధానం: A.
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Question 2 ప్రశ్న 2Answer: C. 200 and 600 mg/L సమాధానం: C.
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Question 3 ప్రశ్న 3Answer: C. Hard సమాధానం: C.
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Question 4 ప్రశ్న 4Answer: B. When hardness is below about 150 mg/L as CaCO3, softening for domestic purposes is not usually required సమాధానం: B.
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Question 5 ప్రశ్న 5Answer: A. Carbonate hardness is the smaller of total hardness and total alkalinity; non-carbonate hardness is total hardness minus carbonate hardness సమాధానం: A.
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Question 6 ప్రశ్న 6Answer: B. 180 and 140 mg/L respectively సమాధానం: B.
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Question 7 ప్రశ్న 7Answer: C. 100 mg/L సమాధానం: C.
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Question 8 ప్రశ్న 8Answer: C. 100 mg/L సమాధానం: C.
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Question 9 ప్రశ్న 9Answer: C. 220 mg/L as CaCO3, hard సమాధానం: C.
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Question 10 ప్రశ్న 10Answer: A. Calcium is precipitated principally as CaCO3 and magnesium as Mg(OH)2 after suitable lime and soda addition సమాధానం: A.
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Question 11 ప్రశ్న 11Answer: B. Ca(OH)2 = 207.2 mg/L and Na2CO3 = 127.2 mg/L సమాధానం: B.
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Question 12 ప్రశ్న 12Answer: A. 2,486.4 kg/day Ca(OH)2 and 1,526.4 kg/day Na2CO3 సమాధానం: A.
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Question 13 ప్రశ్న 13Answer: B. 2,762.7 kg/day lime and 1,606.7 kg/day soda సమాధానం: B.
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Question 14 ప్రశ్న 14Answer: A. One lime equivalent converts bicarbonate alkalinity and an additional lime equivalent supplies hydroxide needed to precipitate magnesium as Mg(OH)2 సమాధానం: A.
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Question 15 ప్రశ్న 15Answer: B. It should not be expected to reduce hardness below about 40 mg/L as CaCO3, whereas ion exchange can produce zero-hardness water సమాధానం: B.
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Question 16 ప్రశ్న 16Answer: A. To add CO2 so that excessive alkalinity and pH are reduced and the softened water is stabilized against undesirable calcium-carbonate precipitation సమాధానం: A.
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Question 17 ప్రశ్న 17Answer: A. Calcium and magnesium ions in the water are exchanged for sodium ions held by the zeolite సమాధానం: A.
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Question 18 ప్రశ్న 18Answer: A. By passing a concentrated sodium chloride solution through the bed సమాధానం: A.
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Question 19 ప్రశ్న 19Answer: B. It principally exchanges Ca2+ and Mg2+ for Na+ and therefore does not constitute general demineralization or major TDS removal సమాధానం: B.
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Question 20 ప్రశ్న 20Answer: A. The sodium cycle releases Na+ and is regenerated with NaCl, while a hydrogen-cycle cation exchanger releases H+ and is regenerated with acid సమాధానం: A.
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Question 21 ప్రశ్న 21Answer: A. Lime-soda softening may be particularly suitable because the precipitation process can handle very high hardness and the turbidity, colour and iron would tend to foul or coat an ion-exchange bed సమాధానం: A.
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Question 22 ప్రశ్న 22Answer: B. 30% untreated and 70% softened సమాధానం: B.
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Question 23 ప్రశ్న 23Answer: C. 200 m3 సమాధానం: C.
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Question 24 ప్రశ్న 24Answer: A. Lime precipitates magnesium as Mg(OH)2 but produces an equivalent calcium non-carbonate salt, which then requires soda ash to precipitate the calcium as CaCO3 సమాధానం: A.
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Question 25 ప్రశ్న 25Answer: D. I, II, III and IV సమాధానం: D.
